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The best (and most famous) guide I've found so far is Sean McLoughlin's Learn TI-83 Plus Assembly in 28 Days. You can read it online here.
Hot_Dog also made a pretty useful (and easy ) set which I've gone into pretty far myself, found in its sub-forum.
Also, if you are a normal person, your first attempt at learning assembly probably won't go well. Most likely in 28 days, you'll look at day 3 and freak, but you'll think you understand it so after you read it, you'll move on. Then when you start getting up around day 6, you'll realize you have no idea what you're doing and you'll take a break.But, when you come back from this break, that is when you will finally succeed and begin to write assembly programs.