I think there used to be CasEmul, but it didn't seem to be a real emulator. It worked similarly to the TI-Nspire student software or something.
I'm still wondering if there wouldn't be any way to send a hacked file to the calculator, even if it required a third-party linking software to be made, like Ndless? It almost seems impossible that there's absolutely no way to launch ASM on these old calcs. After all, we did it with the TI-81 20 years after it came out, even if the calc got no link cable.