You rang?
No, it isn't possible. In fact, the "voltage" displayed in the diagnostic menu is just the same steps roughly translated over. The battery charging/detection hardware doesn't have fine control of the levels exposed anywhere that the OS could tap into.
The steps roughly correspond to High, medium, low, empty, "I'm about to shut off", "I'm shutting off". Sometimes the time between 5-6 can be a few seconds, but most of the time it is shorter. The time between 4-5 can be minutes, or seconds. It is not very precise at the low levels.